Atropisomerism in a thermally switchable, cyclometallated iridium complex
journal contribution
posted on 2014-10-22, 11:17 authored by Ashlee J. Howarth, David L. Davies, Francesco Lelj, Michael O. Wolf, Brian O. PatrickTwo stable diastereomeric atropisomers of a cyclometallated iridium complex containing a pyrene functionalized pyridine imine ligand have been isolated. These are the first fully characterized examples of metal containing atropisomers in which the rotational axis is not between two chelating atoms. The atropisomers can be converted thermally via a rocking motion of the pyrene moiety.
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Citation
Dalton Transactions, 2012, 41 (34), pp. 10150-10152Author affiliation
/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of ChemistryVersion
- AM (Accepted Manuscript)
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Dalton TransactionsPublisher
Royal Society of Chemistryissn
1477-9226eissn
1477-9234Copyright date
2012Available date
2014-10-22Publisher DOI
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http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c2dt31120h#!divAbstractLanguage
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