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Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride

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posted on 2015-10-29, 13:19 authored by Gemma Geary, Eric G. Hope, Kuldip Singh, Alison M. Stuart
The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as an electrophilic fluorinating reagent for the first time to monofluorinate 1,3-ketoesters and difluorinate 1,3-diketones in good isolated yields.

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Citation

Chemical Communications, 2013, 49 (81), pp. 9263-9265

Author affiliation

/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of Chemistry

Version

  • AM (Accepted Manuscript)

Published in

Chemical Communications

issn

1359-7345

eissn

1364-548X

Copyright date

2013

Available date

2015-10-29

Publisher version

http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc44792h#!divAbstract

Notes

The file associated with this record is under a 12-month embargo from publication in accordance with the publisher's self-archiving policy, available at http://www.rsc.org/journals-books-databases/open-access/green-open-access/. The full text may be available through the publisher links provided above.

Language

en

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