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Generalized Mass Action Law and Thermodynamics of Nonlinear Markov Processes
journal contribution
posted on 2017-03-21, 09:59 authored by A. N. Gorban, V. N. KolokoltsovThe nonlinear Markov processes are measure-valued dynamical systems which preserve positivity. They can be represented as the law of large numbers limits of general Markov models of interacting particles. In physics, the kinetic equations allow Lyapunov functionals (entropy, free energy, etc.). This may be considered as a sort of inheritance of the Lyapunov functionals from the microscopic master equations. We study nonlinear Markov processes that inherit thermodynamic properties from the microscopic linear Markov processes. We develop the thermodynamics of nonlinear Markov processes and analyze the asymptotic assumption, which are sufficient for this inheritance.
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Citation
Mathematical Modelling of Natural Phenomena, 2015, 10 (5), pp. 16-46 (31)Author affiliation
/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of MathematicsVersion
- VoR (Version of Record)
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Mathematical Modelling of Natural PhenomenaPublisher
EDP Sciences, Cambridge University Press (CUP)issn
0973-5348eissn
1760-6101Copyright date
2015Available date
2017-03-21Publisher DOI
Publisher version
http://www.mmnp-journal.org/articles/mmnp/abs/2015/05/mmnp201510p16/mmnp201510p16.htmlNotes
Mathematics Subject Classification: 80A30 / 60J25 / 60J60 / 60J75 / 82B40Language
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Keywords
Science & TechnologyLife Sciences & BiomedicinePhysical SciencesMathematical & Computational BiologyMathematics, Interdisciplinary ApplicationsMultidisciplinary SciencesMathematicsScience & Technology - Other TopicsMarkov processnonlinear kineticsLyapunov functionalentropyquasiequilibriumquasi steady stateIRREVERSIBLE REACTIONSCHEMICAL-REACTIONSDETAILED BALANCEPARTICLE-SYSTEMSKINETICSFRAGMENTATIONCOAGULATIONDIFFUSIONEQUATIONSEVOLUTION