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Infrared spectroscopy of Ca(NH3)n complexes

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journal contribution
posted on 2018-09-25, 10:12 authored by Munirah D. Albaqami, Andrew M. Ellis
Infrared spectra of Ca(NH3)n complexes in the gas phase have been recorded for the first time. The spectra are consistent with structures where the Ca atom resides inside one or more solvation shells of NH3 molecules. IR spectra were recorded using a photodissociation technique. A comparison of the spectra with those predicted from ab initio calculations suggests that Ca(NH3)8 has all NH3 molecules in a single solvent shell around the Ca atom, whereas the spectra of Ca(NH3)9 and Ca(NH3)10 are consistent with two-shell structures.

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Citation

Chemical Physics Letters, 2018, 706, pp. 736-740

Author affiliation

/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of Chemistry

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  • AM (Accepted Manuscript)

Published in

Chemical Physics Letters

Publisher

Elsevier

issn

0009-2614

Acceptance date

2018-06-22

Copyright date

2018

Publisher version

https://www.sciencedirect.com/science/article/pii/S0009261418305293

Notes

The file associated with this record is under embargo until 24 months after publication, in accordance with the publisher's self-archiving policy. The full text may be available through the publisher links provided above.

Language

en

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