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Triol protection with 6-benzoyl-3,4-dihydro-(2H)-pyran.

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posted on 2009-12-08, 16:23 authored by Caroline D. L. Baker, John Fawcett, Christopher D. Insley, Derek S. Messenger, Claire L. Newland, Helen L. Overend, Anup B. Patel, Mufakhrul Shah, Bhavna Vara, Davinder Virdee, Bernard J. Rawlings
6-Benzoyl-3,4-dihydro-(2H)-pyran will protect 1,2,3-triols such as glycerol as their corresponding spiro-[5-phenyl-3,6,8-trioxabicyclo[3.2.1]octane-4,2′-tetrahydropyran]s and 1,2,4-triols (less efficiently) as the corresponding trioxabicyclo[3.2.2]nonanes; the hexol mannitol is converted into the corresponding bis-protected product.

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Citation

Chemical Communications, 2005, pp.1883-1885

Version

  • VoR (Version of Record)

Published in

Chemical Communications

Publisher

The Royal Society of Chemistry

issn

1359-7345

eissn

1364-548X

Copyright date

2005

Available date

2009-12-08

Publisher version

http://pubs.rsc.org/en/Content/ArticleLanding/2005/CC/b418035f#!divAbstract

Language

en

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