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trans-Bis{1-[2-(2,6-diisopropyl-anilino)phenyl]-3-isopropyl-imidazolin-2-ylidenyl-κC}diiodidopalladium(II) benzene disolvate.

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posted on 2012-10-24, 09:08 authored by C. G. Daly, K. Singh, W. B. Cross
In the title complex, [PdI(2)(C(24)H(31)N(3))(2)]·2C(6)H(6), the Pd(2+) ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I(2)C(2) square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I-Pd-C-N torsion angles of -81.1 (6) and -78.2 (5)°. The Pd-carbene and Pd-I distances are 2.016 (6) and 2.5971 (10) Å, respectively.

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Citation

Acta Crystallographica Section E: Structure Reports Online, 2011, 67 (Pt 6), p. m668

Version

  • VoR (Version of Record)

Published in

Acta Crystallographica Section E: Structure Reports Online

Publisher

International Union of Crystallography

eissn

1600-5368

Copyright date

2011

Available date

2012-10-24

Publisher version

http://scripts.iucr.org/cgi-bin/paper?S1600536811015431

Language

eng

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